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Preparation and properties of polyimides and polyamide-imides from diisocyanates

✍ Scribed by Mehdi Barikani; Shahram Mehdipour Ataei


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
198 KB
Volume
37
Category
Article
ISSN
0887-624X

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✦ Synopsis


Polyimides of different structures were synthesized by reaction of 1,4phenylene diisocyanate (PPDI) and 1,5-naphthalene diisocyanate (NDI) with pyromellitic dianhydride (PMDA) and 3,3Ј,4,4Ј-benzophenonetetracarboxylic dianhydride (BTDA). Polyamide-imides were also prepared by reaction of PPDI and NDI with trimellitic anhydride. The optimized condition for polymerization reactions were obtained via the study of model compounds. All polymers and model compounds were characterized by conventional methods. Physical properties of polymers, including thermal behavior, thermal stability, solution viscosity, and solubility behavior, were also studied.


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