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Preparation and properties of new polycyclic aliphatic polyamides base on diamantane

✍ Scribed by Yaw-Terng Chern; Jea-Shih Fang; Meng-An Chung

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 397 KB
Volume: 58
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.1995.070580902

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✦ Synopsis

A series of novel polycyclic aliphatic polyamides was synthesized by direct polycondensation of the 1,6-diamantane dicarboxylic acid with various alicyclic diamines in N-methyl-2pyrrolidone (NMP) containing lithium chloride, using triphenyl phosphite and pyridine as a condensing agent. The polyamides had inherent viscosities of 0.33-0.49 dL/g. The glass transition temperatures of the these polyamides were in the range of 2O0-22O0C, and the 5% weight loss temperatures were in the range were 290-319°C in nitrogen. 0 1995

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