Preparation and properties of manganese(II)-and mercury(II)-β″-aluminas
✍ Scribed by G. Róg; W. Pycior; A. Kozŀowska-Róg
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 137 KB
- Volume
- 28-30
- Category
- Article
- ISSN
- 0167-2738
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✦ Synopsis
PREPARATION AND PROPERTIES OF MANGANESE(1D-AND MERCURY(II}-~' -AU2blINAS G. R(~G, W. PYCIOR and A. KOZLOWSKA-ROG R~ived 6 lair 1987 aid. ~e e~ienl of ion r and i[1r ch~l ~6ofi of ~D[es o~iu~ we~ ~[nr ~e ele~d~ ~nde~iv[W ~su~ ~ing u simpM dc ~r-p~ mr ~e ~r~ir ~ndu~ivily was d~a~ed from cu~n(-~tml ~ f~lo~iag me method ~d by W~sner an~ it was ~ound ~ be .eglitible. Tae ion tmmfe~n~ .umbels ~e~ also defined.
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## The results of e.s.r., vibrational and electronic investigations were compared in order to describe the ligand field properties, the charge distribution and the nature of the chemical bonds in the adducts of bis-(2,4-pentanedionato)manganese(II) (Mn(pd)z) with basic molecules. E.s.r. data are sui
## The compounds MnC505 .3H,O with M =Cu (I), Mn (II), Fe (III), were prepared and characterized by means of structural and magnetic measurements. The crystals are orthorhombic, space group Pbca, with a = 11.770( 2), b = 8.085(2), c = 15.571(2) 8, for I, a = 12.063(3), b = 8.213(2), c = 15.652(3)