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Preparation and properties of lithium bis(borane)dimethylphosphide(1-)

✍ Scribed by Keller, Philip C.; Schwartz, Lawrence D.

Book ID
127104204
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
414 KB
Volume
10
Category
Article
ISSN
0020-1669

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Cis and trans 1,2dichloroethylene react with LiPPha [l] and LiAsPha [2, 31 stereospecifically to form the corresponding vinylic diphosphines and diarsines in high yield. However cis 1,2dichloroethylene and NaAsMea produce 1,2-bis(dimethylarsino)ethylene, MeaAsCH = CHAsMea, in approximately 30% with