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Preparation and Properties of Carbonyliron Complexes of 1-Aza-4-oxa-1,3-butadiene (α-Imino Ester). X-ray Crystal Structures of Fe(CO) 2 (σ( N ): σ( C )- i -PrN(H)C(H)C(O)OEt) 2 and Fe(CO) 2 (σ( N ): σ( C )- i -PrN(H)C(H)C(O)OMe)( i -PrNC(H)C(O)O)

✍ Scribed by Siebenlist, Ron; Frühauf, Hans-Werner; Vrieze, Kees; Kooijman, Huub; Smeets, Wilberth J. J.; Spek, Anthony L.


Book ID
126909566
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
313 KB
Volume
19
Category
Article
ISSN
0276-7333

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Preparation and Properties of Carbonylir
✍ Ron Siebenlist; Hans-Werner Frühauf; Kees Vrieze; Wilberth J. J. Smeets; Anthony 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 473 KB 👁 1 views

Coordination chemistry / α-Imino ketones / CO complexes / Iron complexes The reaction of Fe 2 (CO) 9 at room temperature in THF or toluene with the α-imino ketones R 1 N=C(R 2 )-C(R 3 )=O (L) (R 1 = alkyl, R 2 = H, Me, Ph, R 3 = Me, Ph) (a-k), initially results in the formation of the mononuclear ch