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Preparation and EPR Studies of Lithium Phthalocyanine Radical as an Oxymetric Probe

✍ Scribed by Mobae Afeworki; Nathan R Miller; Nallathamby Devasahayam; John Cook; James B Mitchell; S Subramanian; Murali C Krishna


Book ID
114276898
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
113 KB
Volume
25
Category
Article
ISSN
0891-5849

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Preparation and study of a lithium phtha
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A metallophthalocyanine radical, PcLi, was prepared by electrochemical oxidation of the corresponding dianion. The redox properties in solution show that PcLi is both easily reduced and easily oxidized (U?= Ee -ET2 = 0.83 V) . This property is of the utmost importance for obtaining intrinsic molecul