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Preparation and electrochemical properties of double-metal nitrides containing lithium

✍ Scribed by H. Yamane; S. Kikkawa; M. Koizumi


Book ID
103898296
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
347 KB
Volume
20
Category
Article
ISSN
0378-7753

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✦ Synopsis


A study is reported of the preparation, chemical composition, and crystal structure of binary compounds of Li3N with other nitrides, i.e., Mg,N2, AlN, BN, and Si3N4. Most of the crystal structures are related to an antifluorite system. Except for LiMgN, the compounds are pure lithium ion conductors. A new compound, LisSiN,, has the highest lithium ion conductivity (viz., 1 X 10m3 S m-l at 298 K) of the double-metal nitrides investigated.


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Electrochemical behavior of a new class of glass-polymer composites (GPC), consisting of (100-x) ~01% (0.56LizS~0.19B~S,.0.25LiI) glass and x ~01% (P(E0)6.LiN(CF$O&) polymer with x = 7, 13 and 25, has been investigated in cells with different electrodes. Results show that the addition of the polymer