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Preparation and Diels-Alder reaction of some benzoylacrylic acids

โœ Scribed by Bugle, Robert C.; Wheeler, Desmond M. S.; Wheeler, Margaret M.; Hohman, James R.


Book ID
127249967
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
464 KB
Volume
46
Category
Article
ISSN
0022-3263

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Asymmetric Diels-Alder reaction catalyse
โœ F. Rebiere; O. Riant; H.B. Kagan ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 906 KB

Diels-Alder reaction between cyclopentadiene and various dienophiles (mainly methacrolein) at -78ยฐC was catalysed by various chiral aluminum alcoholates. The catalysts were prepared by reaction of EtAICl2 with several families of dial (or their monoether monoalcohol derivatives) . The most enantiose