Preparation and crystal structure of trans-dihydroxo-[tetrakis(2,6-dichlorophenyl)porphinato]ruthenium(IV)·2toluene
✍ Scribed by Patrick Dubourdeaux; Manuella Tavarès; André Grand; René Ramasseul; Jean-Claude Marchon
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 372 KB
- Volume
- 240
- Category
- Article
- ISSN
- 0020-1693
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## The reaction of 2,3,5,6tetrakis(methylene)bicycle [2.2.2]octane (la) with Fez(CO), yields the two (q4-1,3diene)Fe(CO)3 isomers (2: exe; 3:endo) together with two bimetallic isomers (CIZH14)[Fe-(CO)3]2 (4:endo+xo; S:diexo). The reaction of la with RuB(CO)iZ yields the endo-(C1&14)Ru(CO)3 (6) and e
The title compound and its potassium analog have been prepared from corresponding aqueous solutions of 9 T c 0 , at p H z 2 with SO2 as a reducing agent. An X-ray structure determination of the Na-salt showed Tc coordinated to the tetradentate N (CH,COO)Z-ligand (NTA). Two Tc-NTA moieties are joined