✦ LIBER ✦
Preparation and Crystal Structure of Copper(I) Carbonyl Hydrogensulfate, obtained by Carbonylation in Sulphuric Acid
✍ Scribed by Daniela Belli Dell'Amico; Fausto Calderazzo; Luca Labella; Fabio Lorenzini; Fabio Marchetti
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- German
- Weight
- 117 KB
- Volume
- 628
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
✦ Synopsis
The hydrogensulfato-carbonyl derivative [Cu(CO)-(SO 4 H)] n , as obtained from the Cu 2 O/ H 2 SO 4 /CO system and recrystallized from H 2 SO 4 /(CH 3 O) 2 SO 2 has been shown to possess a crystal structure organised in infinite chains built up by corner sharing of {CuO 3 (CO)} and {S(OH)O 3 } tetrahedra. The chains are connected by hydrogen bonds in layers, with CO groups leaning