Preparation and Coordination Complex of the First Imine-Bridged Tetrathiafulvalene−Pyridine Donor Ligand
✍ Scribed by Chahma, M'hamed; Hassan, Nasser; Alberola, Antonio; Stoeckli-Evans, Helen; Pilkington, Melanie
- Book ID
- 120586537
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 106 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
This article describes the synthesis and coordination chemistry of five broad types of ligands containing both phosphorus and sulfur donor centres, reviewing the literature up to the end of 1997. Phosphino thiolate ligands combine a phosphine centre with a thiol functionality (usually deprotonated o
## Abstract The synthesis of the new ligand, BEDT‐TTF‐bipy [4,5‐ethylenedithio‐4′,5′‐(4′‐methyl‐2,2′‐dipyrid‐4‐ylethylenedithio)tetrathiafulvalene] is reported. The first Fe^II^ coordination complex, namely [Fe(NCS)~2~(BEDT‐TTF‐bipy)~2~]**·**CHCl~3~, with this redox‐active ligand is obtained. Magne