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Preparation and Coordination Complex of the First Imine-Bridged Tetrathiafulvalene−Pyridine Donor Ligand

✍ Scribed by Chahma, M'hamed; Hassan, Nasser; Alberola, Antonio; Stoeckli-Evans, Helen; Pilkington, Melanie


Book ID
120586537
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
106 KB
Volume
46
Category
Article
ISSN
0020-1669

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## Abstract The synthesis of the new ligand, BEDT‐TTF‐bipy [4,5‐ethylenedithio‐4′,5′‐(4′‐methyl‐2,2′‐dipyrid‐4‐ylethylenedithio)tetrathiafulvalene] is reported. The first Fe^II^ coordination complex, namely [Fe(NCS)~2~(BEDT‐TTF‐bipy)~2~]**·**CHCl~3~, with this redox‐active ligand is obtained. Magne