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Preparation and Chemical Behavior of 2-(tert-Butoxycarbonyl)amino-3-bromomethyl Pyridine, a Novel Alkylating Agent.

โœ Scribed by Mikhail Krasavin; Sergey Shkavrov; Dmitry Kravchenko


Book ID
101986871
Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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Reaction of metallo S-alkyl N-cyanodithi
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## Abstract Metal salts of __S__โ€alkylโ€__N__โ€cyanodithioiminocarbonates 7 react as __electrophiles__ with hydrazine hydrate to form 5โ€aminoโ€3โ€mercaptoโ€1__H__โ€1,2,4โ€triazole 1. The novel 4โ€cyanothiosemicarbazide 9 is proposed as the intermediate which cyclizes to the aromatic triazole. The rate dete