Preparation and characterization of titanosilicates with ZSM-5 structure

✍ Scribed by Bogdan Sulikowski; Jacek Klinowski

• Book ID: 103962744
• Publisher: Elsevier Science
• Year: 1992
• Tongue: English
• Weight: 812 KB
• Volume: 84
• Category: Article
• ISSN: 0926-860X
• DOI: 10.1016/0926-860x(92)80112-p

✦ Synopsis

A titanosilicate with the crystal structure of xeolite ZSM-5 was prepared via the non-alkaline " fluoride" route using rutile as the source of titanium. The properties of the product are compared with those of silicalite, the purely siliceous analogue of ZSM-5, and a sample prepared by a post-synthesis treatment of silicalite with Tic&. Zeolites [ Si,Ti] -ZSMd selectively catalyse the liquid-phase oxidation of cyclohexanol to cyclohexanone.