Preparation and characterization of thermoresponsive isopropylacrylamide–hydroxyethylmethacrylate copolymer gels

✍ Scribed by H. Çiçek; A. Tuncel

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: English
• Weight: 352 KB
• Volume: 36
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/(sici)1099-0518(199803)36:4<527::aid-pola3>3.0.co;2-m

✦ Synopsis

A random copolymer of N-isopropylacrylamide and 2-hydroxyethylmethacrylate, poly(NIPAM-co-HEMA), having thermoresponsive character was prepared by a redox copolymerization method. Poly(ethylene glycol), PEG 4000 was included in the copolymerization recipe to increase the thermoresponsivity of copolymeric structure. Poly(NIPAM-co-HEMA) copolymer gels having more elastic character and higher mechanical strength relative to poly(NIPAM) gel could be achieved by the proposed copolymerization procedure. The equilibrium and dynamic response against the temperature were investigated for the gel matrices produced by changing the initial NIPAM/HEMA mol ratio and PEG 4000 concentration in the copolymerization mixture. The effective diffusion coefficient of water within the gel matrix was estimated for either swollen or shrunken states by applying an unsteady-state diffusion model on the dynamic swelling and shrinking behaviors of gel matrix prepared in the cylindrical form.