Preparation and characterization of the endohedral metallofullerene Lu@C82
โ Scribed by Houjin Huang; Shihe Yang
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 166 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3697
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โฆ Synopsis
A new metallofullerene Lu@C 82 has been isolated with good purity using polar solvent extraction and HPLC techniques. XPS, EPR and UV-Vis-Nir spectroscopic techniques are employed to characterize the mono-metallofullerene Lu@C 82 . Our results suggest that the encaged Lu atom donates approximately three electrons to the carbon cage.
๐ SIMILAR VOLUMES
Nd@C82 has been isolated with a purity of ~ 99.9% by an efficient solvent extraction procedure, followed by HPLC separation. UV-VIS-NIR absorption spectra of the metallofullerenes were measured in a wavelength range from 300 to 2100 nm. The spectral features are remarkably similar to those of La@Cs2