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Preparation and Characterization of Self-Assembled Nanoparticles Formed by Poly(ethylene oxide)- block -poly(ε-caprolactone) Copolymers with Long Poly(ε-caprolactone) Blocks in Aqueous Solutions

✍ Scribed by Šachl, Radek; Uchman, Mariusz; Matějíček, Pavel; Procházka, Karel; Štěpánek, Miroslav; Špírková, Milena

Book ID: 120649114
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 143 KB
Volume: 23
Category: Article
ISSN: 0743-7463
DOI: 10.1021/la063014c

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## SYNOPSIS Blends of poly(L-lactide) (PLLA) and poly(e-caprolactone) (PCL) were prepared in a corotating twin screw miniextruder (40 rpm, 200"). It was attempted to prepare multiblock copolymers by allowing a controlled number of transesterification reactions. Various catalysts (n-Bu,SnOMe, Sn(Oc