A series of novel metal-containing bismaleimides monomers BMI(M) (M Å Ca, Sr, Ba, Pb, Co, Ni) were prepared by reacting maleic anhydride with diaminodiphenyl carboxylate to form bismaleamic acid precursors, and subsequently by imidizing them chemically or thermally to form bismaleimides. The samples
Preparation and characterization of polyacrylic acid–alkali metal salt complex
✍ Scribed by PeiXin Xu; ZhiZhong Chen; WenMing Xie
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 102 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1042-7147
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✦ Synopsis
Polymeric solid ionic conductor is a new class in functional materials. Its study has grown vigorously in recent years. The polymerization of polyacrylic acid± alkali metal salt complex is studied for the first time. Some important factors and reaction conditions, such as polymerization temperature, concentration of initiator and amount of alkali metal salt, have been discussed. The results, show that the polymerization temperature should be controlled at about 60°C and the best initiator's amount is 0.04±0.05% of the whole weight of materials. The complex has been characterized with infrared spectroscopy, differential scanning calorimetry, conductance ratio and adhesion strength determinations, acute toxicity and skin allergy reaction. This complex is a kind of multifunctional medical conductive adhesive with good performances in medicine, conductive adhesiveness and pressure sensitivity.
📜 SIMILAR VOLUMES
Fig. 3. Projection of the crystal lattice in the direction [OOI]. molecules on its main axis and each of these in turn bonds two further porphinogen moleculesat its periphery. The results of this mode of arrangement is the formation of water-containing. tubular cavities, as depicted in Fig. .
Some 50 metal-containing polyimides with the metallic elements (Mg, Ca, Sr, Ba, Pb, Co, Ni) in the main chain were prepared first by reacting pyromellitic dianhydride (PMDA) with the mixture of divalent metal salts of p-aminobenzoic acid [ABA(M)] and 4, 4'-diaminodiphenylmethane (MDA) to form polyam