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Preparation and characterization of end-reactive oligomers by thermal degradation of polyisobutylene

✍ Scribed by Takashi Sawaguchi; Manabu Seno

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 805 KB
Volume: 37
Category: Article
ISSN: 0032-3861
DOI: 10.1016/0032-3861(96)00171-1

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The thermal degradation of polyisobutylene is characterized by kinetics consisting of four types of intramolecular hydrogen abstraction (back-biting) of primary (p) and tertiary (t) terminal macroradicals (Ri and R;) and the successive scission at the inner position of the main chain. This reaction