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Preparation and characterization of dirhenium complex anions of the type [Re2Cl7(dithioether)]− with ReRe quadruple bonds

✍ Scribed by Bruce J. Heyen; J.Gregory Jennings; Gregory L. Powell


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
544 KB
Volume
229
Category
Article
ISSN
0020-1693

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The redox chemistry of the triply bonded
✍ Irene Ara; Richard A. Walton 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 876 KB

The current literature on multiply bonded dirhenium complexes that contain the bis(dimethylphosphino)methane ligand (abbreviated dmpm) is reviewed. New procedures are described for the synthesis of the complex Re,Cl&dmpm),. The analogous bromide and iodide complexes of stoichiometry Re&(~-dmpm)3 hav