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Preparation and Characterization of Blue-Luminescent Tris(8-hydroxyquinoline)-aluminum (Alq3)

✍ Scribed by M. Cölle; J. Gmeiner; W. Milius; H. Hillebrecht; W. Brütting


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
188 KB
Volume
13
Category
Article
ISSN
1616-301X

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High-Efficiency Tris(8-hydroxyquinoline)
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## Abstract Combinations of electron‐withdrawing and ‐donating substituents on the 8‐hydroxyquinoline ligand of the tris(8‐hydroxyquinoline)aluminum (Alq~3~) complexes allow for control of the HOMO and LUMO energies and the HOMO–LUMO gap responsible for emission from the complexes. Here, we present

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Tris(8-hydroxyquinoline)aluminum (AlQ) powder has been characterized using photoluminescence and electron spin resonance (ESR). The broad asymmetric excitation band is centered at ∼425 nm, while the emission band centered at ∼505 nm is similar to those reported in films. A significant ESR signal wit