Preparation and characterization of a bis-galvinoxyl-disulfide
โ Scribed by David A. Shultz; Qi Zhao
- Book ID
- 104255863
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 213 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Ahtruck
The synthesis of a biradical r&sulfide is described. This biradical exhibits an EPR spectrum consistent with lJl>>n . Cyclic voltammetry of monolayers of this biiadical shows that the radical monolayer exhibits less pHdependence than its phenol counterpart Copyright 0 1996 Elsevier Science Ltd Multilayers are uniquely suited to serve as molecular magnets' since they provide a direct linkbetween surfaces and magnetic properties, that is, magnetic information storage.2J An important design element of our multilayer scheme is the use of paramagnetic ligands. With this approach we can take advantage of large paramagnetic-ligand to metal antiferromagnetic exchange couplings to yield high-T, ferrimagnetic materials.
๐ SIMILAR VOLUMES
## Abstract The stable galvinoxyl radical has been prepared with specific deuterium substitution at the methylene carbon bridge between the two aromatic rings. The corresponding EPR spectrum illustrates only the small residual hyperfine coupling with the aromatic ring hydrogens.
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