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Preparation and characterization of a bis-galvinoxyl-disulfide

โœ Scribed by David A. Shultz; Qi Zhao


Book ID
104255863
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
213 KB
Volume
37
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Ahtruck

The synthesis of a biradical r&sulfide is described. This biradical exhibits an EPR spectrum consistent with lJl>>n . Cyclic voltammetry of monolayers of this biiadical shows that the radical monolayer exhibits less pHdependence than its phenol counterpart Copyright 0 1996 Elsevier Science Ltd Multilayers are uniquely suited to serve as molecular magnets' since they provide a direct linkbetween surfaces and magnetic properties, that is, magnetic information storage.2J An important design element of our multilayer scheme is the use of paramagnetic ligands. With this approach we can take advantage of large paramagnetic-ligand to metal antiferromagnetic exchange couplings to yield high-T, ferrimagnetic materials.


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## Abstract The stable galvinoxyl radical has been prepared with specific deuterium substitution at the methylene carbon bridge between the two aromatic rings. The corresponding EPR spectrum illustrates only the small residual hyperfine coupling with the aromatic ring hydrogens.

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