Preparation and Analysis of Phenol-Formaldehyde Resins by High-Throughput Techniques
โ Scribed by Harald Pasch; Matthias Schrod
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 293 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1022-1336
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โฆ Synopsis
Abstract
Summary: Phenolic resin composition depends on monomer ratio, catalyst, reaction conditions, and residual free monomers. Using a simple device for parallel synthesis, large numbers of samples of different compositions were prepared. Residual free phenol and formaldehyde were determined by fast HPLC. Using this approach, combinatorial libraries for a huge variety of different experimental conditions can be developed. These libraries bear information on the effect of different experimental parameters on resin composition.
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Corn bran (CB) was liquefied in the presence of phenol at high temperature (200ยฐC) under high pressure (ฯพ1 atm) and the obtained liquefied products were reacted with formaldehyde to get phenolated CB/phenol/formaldehyde resins with excellent yields. The properties of the cocondensed resins were exam
## Abstract Phenolโureaโformaldehyde (PUF) resins were synthesized by reacting mixture of methylolureas (MMU), phenol, and formaldehyde. The structure of PUF cocondensed resins at different stages of reaction were analyzed by liquid ^13^C nuclear magnetic resonance (NMR) spectroscopy. The liquid ^1