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Preferential solvation of silver(I), copper(I) and copper(II) ions in aqueous acetonitrile

โœ Scribed by Marcus, Yizhak


Book ID
111898156
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
609 KB
Volume
9
Category
Article
ISSN
1472-7773

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The formal standard potentials of the Cu/Cu', Cu/Cu'+, Ag/Ag+ and Au/Au+ couples have been measured in acctonitrile, propionitrile and benzonitrile in 0.1 mol drne3 tetraethylammonium perchlorate medium at 25ยฐC. The emfdata were used to estimate the Gibbs free energies of Cu\*, Cu2\*, Ag+ and Au+ tr

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## Abstrad -The diffusion coefficients of Cu(I), Ag(I) and Au(I) ions in molten KC1 were found to be 2.14 f 0.35, 2.03 f 0.08 and 2.2 x lo-' cma/s respectively by chronopotentiometry with a Pt indicator and Pt reference electrode. R&sum&-Les coefficients de diffusion respectifs des ions Cu(I), A&I