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Preferential solvation of copper(II) salts in water—pyridine and water—dimethyl sulphoxide mixtures

✍ Scribed by G. Rajendran; T.K. Sreekumar; C. Kalidas

Book ID
107992470
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
596 KB
Volume
46
Category
Article
ISSN
0378-3812

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Polarographic studies of copper(II) in a
Polarographic studies of copper(II) in aqueous dimethylsulphoxide and aqueous acetone and free energy of transfer of copper(I) and copper(II) from water to dimethyl-sulphoxide-water mixtures
✍ D.M. Muir; C. Kenna; P. Singh 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 250 KB

Polarographic studies of Cu(CIO,), in aqueous dimethylsulphoxide (DMSO) mixtures have identified compositions in which Cu(l) is stable. The half-wave potentials, E,,,, of Cu(II)/Cu(I) and Cu(I)/Cu(Hg) decrease in DMSO-water mixtures and values of free energies of transfer, AG,., of Cu(II) and Cu(I)