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Preferential grafting of alkoxysilane coupling agents on the hydrophobic portion of the surface of micelle-templated silica

✍ Scribed by Brunel, Daniel; Cauvel, Anne; Di Renzo, Francesco; Fajula, François; Fubini, Bice; Onida, Barbara; Garrone, Edoardo


Book ID
121403899
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
173 KB
Volume
24
Category
Article
ISSN
1144-0546

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The surface of colloidal silica of 22 nm and 100 nm in diameter has been modified with a silane coupling agent, n-octadecyltriethoxysilane. The solid state 13C NMR spectrum shows surprisingly that the covalently bonded n-octadecyl chains on the silica surface adopt largely extended all-rrans confor