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Predominance of the Participation of the Geminal over Vicinal Bonds: Torquoselectivity of Retro-Nazarov Reactions

✍ Scribed by Naruse, Yuji; Ichihashi, Yu; Shimizu, Takashi; Inagaki, Satoshi


Book ID
111918057
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
798 KB
Volume
14
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Geminal Bond Partic
✍ Satoshi Inagaki; Hirotaka Ikeda πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB πŸ‘ 2 views

Geminal Bond Participation and Reactivities of Z-vs E-1-Substituted Butadienes in the Diels-Alder Reactions. -Analysis of the electronic structures of the transition states in Diels-Alder reactions of butadienes (I)-(VI) with ethylene discloses the significant participation of the geminal Οƒ bonds at