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Predissociation dynamics of He79Br2 and Ne79Br2; test of product state propensity rules

✍ Scribed by N. Sivakumar; J.I. Cline; C.R. Bieler; K.C. Janda

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 376 KB
Volume: 147
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80268-9

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✦ Synopsis

Product state distributions for the predissociation of the van der Waais molecules He79BrZ and Ne79Br, in their respective B excited electronic states are reported. The partitioning of energy between the rotational and translational degrees of freedom observed for these molecules, and also that previously reported for HeClr and NeCl,, is compared to that predicted by Ewing's propensity rules for vibrational energy transfer. For this set of molecules the rules correctly predict that the V-T channel must account for most of the excess available energy but underestimate the participation of the V-R channel in the dissociation.

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