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Predissociation and hyperfine structure of the B3Πou+ state of Br2

✍ Scribed by M. Siese; E. Tiemann; U. Wulf

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
411 KB
Volume
117
Category
Article
ISSN
0009-2614

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✦ Synopsis

Using mola~lar-bum laser spectroscopy. Ihe hypcrfiit structure of the B-X system of -Br, was measured to oblain reixshlt &?a on hype&x and rowztlonal predw~&ation for the kvcls Et(O;) u-11, 13 and 16. We 'cp0t-t the first m=urrrnCnt of the hypcrfinc pral i55uziation with no rotational predissociation on p(1) transitions. The unexpected strongly J-dependent variation of the predkocialion parameters leads to the conclusion that the familiar theory dexribing all known dala for Lhc El state of iodine may be inadequate for bromine

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