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Predictions of Geometries and Multiplicities of the Manganese−Oxo Intermediates in the Jacobsen Epoxidation

✍ Scribed by Strassner, Thomas; Houk, K. N.

Book ID
120631672
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
52 KB
Volume
1
Category
Article
ISSN
1523-7060

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Symchiral (salen)Mn(lll)CI complexes catalyze the epoxidation of 2sulfonyl, 1,3 cyclic dienes with exceptional enantioselectivity. The incorporation of the sulfone moiety increases the enantioselectivity by up to 30%, relative to the unsubstituted cyclic 1,3-diene.