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Prediction of the Rate Constants for Proton Abstraction from Carbon Acids, Using a Simple Model and Multidimensional Marcus Theory

โœ Scribed by Guthrie, J. Peter

Book ID
127005512
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
61 KB
Volume
119
Category
Article
ISSN
0002-7863

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A simple model for the energy surface of a reacting system permits the calculation of the free energies of activation. A chemical reaction is analyzed in terms of the simple processes (bond making/breaking or atom transfer; geometry changes) which must take place to achieve the overall transformatio