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Prediction of the radiation term in the thermal conductivity of crosslinked closed cell polyolefin foams

✍ Scribed by O. A. Almanza; M. A. Rodríguez-Pérez; J. A. De Saja


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
247 KB
Volume
38
Category
Article
ISSN
0887-6266

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✦ Synopsis


The thermal conductivity and the cellular structure as well as the matrix polymer morphology of a collection of chemically crosslinked low-density closed cell polyolefin foams, manufactured by a high-pressure nitrogen gas solution process, have been studied. With the aid of a useful theoretical model, the relative contribution of each heat-transfer mechanism (conduction through the gas and solid phases and thermal radiation) has been evaluated. The thermal radiation can be calculated by using a theoretical model, which takes into account the dependence of this heat-transfer mechanism with cell size, foam thickness, chemical composition, and matrix polymer morphology. A simple equation, which can be used to predict the thermal conductivity of a given material, is presented.