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Prediction of Solvent Diffusivities in Amorphous Polymers by Free-Volume Theory: Group Contribution and PALS Methods

โœ Scribed by Lv, Hong-ling; Wang, Bao-guo; Kong, Ying

Book ID
111777266
Publisher
Nature Publishing Group
Year
2009
Tongue
English
Weight
179 KB
Volume
41
Category
Article
ISSN
0032-3896

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โœ W. H. Jiang; R. Han ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 190 KB ๐Ÿ‘ 3 views

Several versions of free-volume theory have been proposed to correlate or predict the solvent diffusion coefficient of a polymer/solvent system. The quantity of free volume is usually determined by the Williams-Landel-Ferry (WLF) equation from viscosity data of the pure component in these theories.