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Prediction of mass transport profiles in a laboratory filter-press electrolyser by computational fluid dynamics modelling

✍ Scribed by L. Vázquez; A. Alvarez-Gallegos; F.Z. Sierra; C. Ponce de León; F.C. Walsh


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
883 KB
Volume
55
Category
Article
ISSN
0013-4686

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✦ Synopsis


A commercial computational fluid dynamics code (Fluent) has been used to analyze the performance of a unit cell laboratory; the filter-press reactor (FM01-LC) operating with characteristic linear flow velocities between 0.024 m s -1 and 0.110 m s -1 . The electrolyte flow through the reactor channel was numerically simulated using a finite volume approach to the solution of the Navier-Stokes equations. The flow patterns in the reactor were obtained and the mean linear electrolyte velocity was evaluated and substituted into a general mass transport correlation to calculate the mass transport coefficients. In the region of 150 < Re < 550, mass transport coefficients were obtained with a relative error between 5% and 29% respect to the experimental k m values. The differences between theoretical and experimental values are discussed.