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Prediction of hydrate formation for systems containing methanol

✍ Scribed by Yaho Du; Tian-Min Guo


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
666 KB
Volume
45
Category
Article
ISSN
0009-2509

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✦ Synopsis


To reduce the risk of hydrate formation, methanol is the most commonly used inhibitor. A modified Peng-Robinson (PR) model based on Mollerup's random-nonrandom (RNR) theory was developed to describe the vapor-liquid equilibria of strongly polar methanol-water-gas systems under pressure. The new model (PR-RNR model), as coupled with the simplified version of the Holder-John three-shell hydrate equilibrium model proposed by the authors, has been successfully used to predict the effect of methanol concentration on hydrate formation of pure gases and gas mixtures. 'AAD (%) = (l/N,) c l(P, -PJ/P,Ij x 100. j *(a) Meyer et al. (1967), (b) Kraus and Greer (1984), (c) Ambrose and Sprake (1970).


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