𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Prediction of chirality of major product by models of diop-rhodium(I) complexes for asymmetric hydrogenation and hydrosilylation

✍ Scribed by Robert Glaser

Publisher
Elsevier Science
Year
1975
Tongue
French
Weight
212 KB
Volume
16
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Kagan's (+) or (-) 2,3-0-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane 1,2 (DIOP) (I) ligand has been used in both rhodium-catalyzed asymmetric hydrogenation'-' and hydra.

silylation 5-8 reactions. Space-filling CPK-type molecular models were made of (+) DIOP-Rh(1)

πŸ“œ SIMILAR VOLUMES

Structural requirements in chiral diphos
Structural requirements in chiral diphosphine-rhodium complexes. VIII. Asymmetric hydrogenation of N-acetyldehydroamino acids with rhodium(I) complexes containing chiral carbocyclic analogues of DIOP.
✍ Robert Glaser; Menachem Twaik; Shimona Geresh; Jeanine Blumenfeld πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 French βš– 289 KB

Z-a-acetamidocinnamic acid was hydrogenated with neutral diphosphine-rhodium(I) complexes containing trans-1,2-bis(diphenylphosphinomethy1)cycloalkanes