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Predicting the Liquid-Vapor Critical Point from the Crystal Anharmonicity

โœ Scribed by Y. Rosenfeld

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
102 KB
Volume
41
Category
Article
ISSN
0005-8025

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โœฆ Synopsis

A 'universal' dependence is predicted of the reduced critical parameters (temperature, density, and pressure) on the crystal anharmonicity. The model, which employs the 'universal' zero-temperature equation of state in a version of fluid perturbation theory, is apparently the first to predict correctly the critical temperature and density for both the rare gases and Alkali metals.

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