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Precursors and trapping in the molecular chemisorption of CO on Ni(100)

✍ Scribed by Mark P. D'evelyn; Hans-Peter Steinrück; Robert J. Madix


Publisher
Elsevier Science
Year
1987
Weight
80 KB
Volume
180
Category
Article
ISSN
0167-2584

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Precursor-mediated dissociative chemisor
✍ X.-Y. Zhu; J.M. White 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 493 KB

We report evidence for precursor dynamics in the dissociative chemisorption of Dz on Ni( 100) partially covered by CO. Effcient energy transfer from incident Dz to surface CO and the transient bonding of Dz to CO-modified Ni sites are invoked to explain the significant role played by precursor speci