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Precursor directed biosynthesis of novel 6-deoxyerythronolide B analogs containing non-natural oxygen substituents and reactive functionalities

✍ Scribed by Daniel Hunziker; Nicholas Wu; Kenji Kenoshita; David E. Cane; Chaitan Khosla


Book ID
104260504
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
258 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


Feeding of synthetic precursors to a blocked mutant of 6-deoxyerythronoltde B synthase (DEBS) [1] led to production of novel 6-deoxyerythronolide B analogs in vivo containing additional non-natural oxygen substituents as well as additional reactive groups.