Precision Polymer Synthesis by Degenerative Transfer Controlled/Living Radical Polymerization Using Organotellurium, Organostibine, and Organobismuthine Chain-Transfer Agents
β Scribed by Yamago, Shigeru
- Book ID
- 120331636
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 564 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0009-2665
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π SIMILAR VOLUMES
## Abstract Living radical polymerization of lauryl acrylate was achieved by SET/DTLRP in water catalyzed by sodium dithionite. The work describes the synthesis of a highly hydrophobic and polar monomer in aqueous medium. The plots of $\overline M \_{\rm n}$ versus conversion and ln[M]~0~/[M] versu
Epoxy-terminated polystyrene has been synthesized by radical polymerization using a-( tbutylperoxymethyl) styrene (TPMS) as the chain transfer agent. The chain transfer constants were found to be 0.66 and 0.80 at 60 and 70Β°C, respectively. The presence of epoxy end groups was confirmed by functional