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Precision measurements of osmotic pressure in concentrated polymer solutions—II

✍ Scribed by H. Vink


Book ID
107753338
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
476 KB
Volume
10
Category
Article
ISSN
0014-3057

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Precision measurements of osmotic pressu
✍ H. Vink 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 442 KB

Precision measurements of osmotic pressure have been carried out with several polymers (dextran, hydroxyethyl cellulose, polyvinylpyrrolidone and polyethlene oxide) in aqueous solutions. The concentration dependence of the osmotic pressure over a wide range of concentrations (up to 0-2 g/cm 3) was e

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Concentrated solutions of poly(vinyl acetate)/toluene and poly(dimethyl siloxane)/octane were investigated in the polymer volume fraction range 0.08 ~ ¢ ~< 0.5 using small angle X-ray scattering. As the concentration increases the polymer-polymer correlation length deviates increasingly from the pre

A Simple Relation for the Concentration
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## Abstract We propose simple expressions $\Pi /\Pi \_0 = 1 + (\varphi /\varphi \_{{\rm ex}} )^{3\alpha - 1}$ and $(\delta \_0 /\delta )^2 = 1 + (\varphi /\varphi \_{{\rm ex}} )^{2\alpha }$ for the osmotic pressure Π and the depletion thickness __δ__ as a function of the polymer concentration __φ__