Precipitation of proteins in supercritical carbon dioxide
โ Scribed by Michael A. Winters; Barbara L. Knutson; Pablo G. Debenedetti; H. Gerald Sparks; Todd M. Przybycien; Cynthia L. Stevenson; Steven J. Prestrelski
- Book ID
- 109388497
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 365 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0022-3549
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Solubilities of a model compound (nicotinic acid) in pure supercritical carbon dioxide (SC-CO 2 ) and SC-CO 2 modiยฎed with methanol have been measured in the pressure range of 80ยฑ200 bar and between temperatures of 35 and 908C. On-line ultraviolet detection enabled a simple and relatively fast measu
## Abstract Nitroxideโmediated controlled/living radical precipitation polymerization of styrene in supercritical carbon dioxide has been performed using SG1 and AIBN as mediator and initiator, respectively. The equivalent bulk polymerization proceeded at a rate โ1.58 times faster than the precipit