Practical Synthesis of Myrcene Derivatives Possessing Oxidized Methyl Groups
β Scribed by Naito, Makoto; Ezoe, Akihiro; Kimura, Masanari; Tamaru, Yoshinao
- Book ID
- 127317007
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 47 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The preparation of fluoromethylated optically pure trans 0 epoxycompounds (CXFZ-Ci-\CH-C (0) R, X=F,H or Cl ; R=OEt, Ph, t-Ru, C (OH) Me21 from the corresponding B -hydroxyketones and/or esters is described.
## Abstract Acetylenes that possess two bulky alkyl substituents reacted with sulfur dichloride to furnish the corresponding 2,3βdialkylβ2,3βdichlorothiiranes (**__5__**) nearly quantitatively. The alkaline hydrolysis of **__5__** afforded 2,3βdialkylthiirene 1βoxides (**__10__**) in high yields. T