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Practical Synthesis of KRN7000 from Phytosphingosine.

✍ Scribed by Sanghee Kim; Soyoung Song; Taeho Lee; Sungkyu Jung; Deukjoon Kim

Book ID
101963614
Publisher
John Wiley and Sons
Year
2004
Weight
61 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

πŸ“œ SIMILAR VOLUMES

Diastereoselective epoxidation of the do
Diastereoselective epoxidation of the double bond at C-4 of sphingosines to provide phytosphingosine relatives such as Ξ±-galactosylceramide KRN7000
✍ Hirosato Takikawa; Shin-etsu Muto; Kenji Mori πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 746 KB

Diastereoselcctive epoxidation of the double bond at C-4 of two sphingosine derwat1ve.r [J, R = (CHzhMe or (CH2)t2Me] was studied. Dimcthyldioxirane was found to be the best oxidant for that purpose. Application of this epoxidation resulted in a new synthesis of the a-galactosylceramidr KRN7000 (2).