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Practical Synthesis of Enantiopure Spiro[4.4]nonane C-(2′-Deoxy)ribonucleosides.

✍ Scribed by Ryan Hartung; Leo A. Paquette

Publisher
John Wiley and Sons
Year
2005
Weight
13 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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Synthesis of homochiral spiro [4.4]nonan
Synthesis of homochiral spiro [4.4]nonane-l,6-diols
✍ Jiang Yao-Zhong; Yan Minga; Sun Jian; Hu Wen-Hao; Li Zhi; Mi Ai-Qiao; Chan Alber 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB 👁 1 views

## Abstract Homochiral __cis, cis‐; cis,trans__ and __trans,trans‐spiro__[4,4]‐nonane‐1,6‐diols were prepared via diastereoselective reduction of enantiomerically pure spiro[4.4]nonane‐l,6‐dione (1) with the corresponding reducing agents: lithium n‐butyldiisobutylaluminium hydride for __cis,cis__‐d