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Practical Stereo- and Regioselective, Copper(I)-Promoted Strecker Synthesis of Sugar-Modified α,β-Unsaturated Imines.

✍ Scribed by Guobin Zhou; Weixin Zheng; Dong Wang; Pengfei Zhang; Yuanjiang Pan


Publisher
John Wiley and Sons
Year
2006
Weight
18 KB
Volume
37
Category
Article
ISSN
0931-7597

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Practical Stereo- and Regioselective, Co
✍ Guobin Zhou; Weixin Zheng; Dong Wang; Pengfei Zhang; Yuanjiang Pan 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 94 KB

## Abstract The regio‐ and stereoselective, __Lewis__ acid catalyzed __Strecker__ reaction between Me~3~SiCN and different aldimines incorporating a 2,3,4,6‐tetrakis‐__O__‐pivaloyl‐D‐glucopyranosyl (Piv~4~Glc) chiral auxiliary has been worked out. Depending on the conditions used, high yields (up t