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Powder processing and densification behaviour of alumina–high zirconia nanocomposites using chloride precursors

✍ Scribed by Raghunath P. Rana; Swadesh K. Pratihar; Santanu Bhattacharyya


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
248 KB
Volume
190
Category
Article
ISSN
0924-0136

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✦ Synopsis


Al 2 O 3 -ZrO 2 composites having nominal equal volume fraction of Al 2 O 3 and ZrO 2 were prepared from gel-precipitated powder, precipitated powder and washed precipitated powder. These different processing routes affected the crystallization temperature of the amorphous powder as well as the phase evolution of Al 2 O 3 and ZrO 2 during calcination. The agglomerate size was largest for gel-precipitated powder (30 m) and it was smallest for washed precipitated powder (19 m). While gel-precipitated powder produce hard agglomerated powder (P j = 110 MPa), washed precipitated powder produce soft agglomerates with low agglomeration strength (P j = 70 MPa). Thus, washed precipitated powder could sinter to a high density at lower sintering temperature. The bending strength exhibits a semi logarithmic relationship with porosity. The hardness shows an increasing trend with sintering temperature.