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Potentiometric study of the protonation equilibrium of Tris(Hydroxymethyl) aminomethane in aqueous sodium perchlorate solutions at 25°C: construction of a thermodynamic model

✍ Scribed by R. Gil; M.S. Corbillón; M.A. Olazabal; J.M. Madariaga


Book ID
117224031
Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
402 KB
Volume
44
Category
Article
ISSN
0039-9140

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The interaction in water of cyclomaltohexaose (a-cyclodextrin) with monocarboxylic acids from C 3 to C12 has been studied calorimetrically at 25 °C in phosphate buffer, pH 11.3. When a complex forms, calorimetry enables the calculation of both the enthalpy and the association constant, from which th