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Potentiometric Estimation of the Stability Constants of Ion−Ionophore Complexes in Ion-Selective Membranes by the Sandwich Membrane Method: Theory, Advantages, and Limitations

✍ Scribed by Shultz, Mikhail M.; Stefanova, Olga K.; Mokrov, Sergey B.; Mikhelson, Konstantin N.


Book ID
121311025
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
89 KB
Volume
74
Category
Article
ISSN
0003-2700

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Two computerized potentiometric methods have been used to determine the stability constants of Na+ , K', and NH: complexes with 18-crown-6 in methanol-water solutions (70% volume fraction of methanol) at 25.0 ? O.l"C, and at constant ionic strength I = 0.1 M, adjusted with tetrabutylammonium iodide