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Potentiometric and Thermodynamic Studies of 4-Sulfamethazineazo-3-methyl-1-phenyl-2- pyrazolin-5-one and Its Metal Complexes

✍ Scribed by Ahmed T. Mubarak


Book ID
111594939
Publisher
Springer US
Year
2004
Tongue
English
Weight
74 KB
Volume
33
Category
Article
ISSN
0095-9782

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Potentiometric and thermodynamic studies
✍ A. S. Fouda; A. A. Al-Sarawy; E. E. El-Katori πŸ“‚ Article πŸ“… 2006 πŸ› Versita 🌐 English βš– 235 KB

## Abstract The dissociation constants of 3-methyl-1-phenyl-{p-[N-(pyrimidin-2-yl)sulfamoyl]phenylazo}-2-pyrazolin-5-one and metal-ligand stability constants of its complexes with some transition metal ions have been determined potentiometrically in 0.1 M-KCl and ethanolβ€”water mixture (30 vol. %).

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R 80 Ph f C6H4CH3-(2) c C,jH,CH3-(4) h d C,H40CH3-(2) i 1037 -HCN 7 R C,H40H-(4) C, H, NH, -(4) ' ? J C d N H R t CpH4N02-(4) C6H4CI-(2) I Key Word: 2-Pyrazolin-5-one derivatives e attack of the amine at the cyclic amide carbonyl function should afford 6 by ring opening and recyclization. Alternatel