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Potential switching of optical properties in polymer electrolytes

✍ Scribed by Tatsuo Fujinami; Mary Anne Mehta; Yasuhisa Yamada; Mitsuo Hiramatsu; Isuke Hirano

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 162 KB
Volume: 35
Category: Article
ISSN: 0887-6266
DOI: 10.1002/(sici)1099-0488(19970930)35:13<2057::aid-polb6>3.0.co;2-t

No coin nor oath required. For personal study only.

✦ Synopsis

The electric field dependence of the optical properties of a series of anionconducting polymer electrolytes at an ITO-electrolyte interface was investigated. A change in reflectance and refractive index of polymer electrolytes [poly(ethyl methacrylate)] 18 (Bu 3 SnX) 3 Bu 4 NX where X Å Cl, Br, and SCN was observed. This was ascribed to anion accumulation/depletion in the interfacial region. Shorter response times were observed for electrolytes with higher conductivities, illustrating the interrelationship between these two phenomena.

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